TY - JOUR
T1 - Observation of Polar Vortices in Oxide Superlattices
JF - Nature
Y1 - 2018/03//
SP - 198
EP - 201
A1 - Ajay K. Yadav
A1 - Christopher T. Nelson
A1 - Shang-Lin Hsu
A1 - Zijian Hong
A1 - James D. Clarkson
A1 - Christian M. Schlepüetz
A1 - Anoop R. Damodaran
A1 - Padraic Shafer
A1 - Elke Arenholz
A1 - Liv R. Dedon
A1 - Deyang Chen
A1 - Ashvin Vishwanath
A1 - Andrew M. Minor
A1 - Long-Qing Chen
A1 - James F. Scott
A1 - Lane W. Martin
A1 - Ramamoorthy Ramesh
KW - Electronic properties and materials
KW - Ferroelectrics and multiferroics
KW - interfaces and thin films
KW - surfaces
AB - The complex interplay of spin, charge, orbital and lattice degrees of freedom provides a plethora of exotic phases and physical phenomena. In recent years, complex spin topologies have emerged as a consequence of the electronic band structure and the interplay between spin and spin–orbit coupling in materials. Here we produce complex topologies of electrical polarization—namely, nanometre-scale vortex–antivortex (that is, clockwise–anticlockwise) arrays that are reminiscent of rotational spin topologies—by making use of the competition between charge, orbital and lattice degrees of freedom in superlattices of alternating lead titanate and strontium titanate layers. Atomic-scale mapping of the polar atomic displacements by scanning transmission electron microscopy reveals the presence of long-range ordered vortex–antivortex arrays that exhibit nearly continuous polarization rotation. Phase-field modelling confirms that the vortex array is the low-energy state for a range of superlattice periods. Within this range, the large gradient energy from the vortex structure is counterbalanced by the corresponding large reduction in overall electrostatic energy (which would otherwise arise from polar discontinuities at the lead titanate/strontium titanate interfaces) and the elastic energy associated with epitaxial constraints and domain formation. These observations have implications for the creation of new states of matter (such as dipolar skyrmions, hedgehog states) and associated phenomena in ferroic materials, such as electrically controllable chirality.
VL - 530
ER -
TY - JOUR
T1 - Strain-Induced Nonsymmorphic Symmetry Breaking and Removal of Dirac Semimetallic Nodal Line in an Orthoperovskite Iridate
JF - Physical Review B
Y1 - 2016/02//
A1 - Jian Liu
A1 - Dominik Kriegner
A1 - Lukáš Horák
A1 - Danilo Puggioni
A1 - Claudy R. Serrao
A1 - Renkun Chen
A1 - Di Yi
A1 - Carlos Frontera
A1 - Vaclav Holy
A1 - Ashvin Vishwanath
A1 - James M. Rondinelli
A1 - Xavier Marti
A1 - Ramamoorthy Ramesh
KW - Dirac semimetal
KW - Electronic structure
KW - Iridates
KW - LDA
KW - thin films
KW - x-ray diffraction
AB - By using a combination of heteroepitaxial growth, structure refinement based on synchrotron x-ray diffraction, and first-principles calculations, we show that the symmetry-protected Dirac line nodes in the topological semimetallic perovskite SrIrO3 can be lifted simply by applying epitaxial constraints. In particular, the Dirac gap opens without breaking the Pbnm mirror symmetry. In virtue of a symmetry-breaking analysis, we demonstrate that the original symmetry protection is related to the n-glide operation, which can be selectively broken by different heteroepitaxial structures. This symmetry protection renders the nodal line a nonsymmorphic Dirac semimetallic state. The results highlight the vital role of crystal symmetry in spin-orbit-coupled correlated oxides and provide a foundation for experimental realization of topological insulators in iridate-based heterostructures.
VL - 93
ER -